02 July, 2025
Terbium
Fri 04 Jul, 2025
Introduction
- Indian scientists at the Indian Institute of Science (IISc), Bengaluru have developed an innovative paper-based glowing sensor that uses the green fluorescence of terbium, a rare earth metal, to aid in the early detection of liver cancer. This discovery not only marks a breakthrough in biomedical diagnostics but also brings to light the unique properties of terbium, an element with growing importance in the field of advanced electronics and magnetics.
What is Terbium?
- Terbium (Symbol: Tb, Atomic Number: 65) is a rare-earth metal belonging to the lanthanide series of the periodic table. It is a moderately hard, silvery-white metal, known for its green luminescence and unique magnetic properties.
Key Physical and Chemical Properties:
Property | Description |
Appearance | Silvery-white, moderately hard metal |
Oxidation States | +3 (most stable), also forms +4 in mixed oxides |
Air Stability | Stable in air due to oxide layer (Tb₂O₃ and TbO₂) |
Solubility | Reacts with dilute acids, insoluble in HF due to formation of TbF₃ |
Magnetic Behavior | Paramagnetic above 230 K, antiferromagnetic (220–230 K), ferromagnetic <220 K |
Biomedical Breakthrough: Liver Cancer Sensor
- The IISc-developed sensor utilizes the green glow of terbium to detect biomolecular changes linked with liver cancer. This sensor is low-cost, simple, and paper-based, making it suitable for early-stage diagnostics even in rural or resource-poor settings.
How It Works:
- When specific biomarkers associated with liver cancer are present, terbium ions embedded in the sensor emit a green fluorescence, providing a visual indicator of possible cancer presence.
Applications of Terbium
1. Electronics and Display Technology:
- Terbium compounds are crucial in green phosphors, used in:
-
- Fluorescent lamps
- Cathode-ray tubes (CRTs)
- LED lighting
- Computer monitors and TV screens
2. Magnetostrictive Materials:
- Alloys of terbium with dysprosium and iron are used in Terfenol-D, a magnetostrictive material widely used in:
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- Sonar systems
- Precision actuators
- Vibration dampers
3. Nuclear Technology:
- Terbium is found in nuclear fission products, contributing to its extraction from nuclear reprocessing waste.
Occurrence and Extraction
- Terbium is not found freely in nature but is derived from rare-earth minerals like:
Mineral Source | Main Ores | Presence |
Bastnasite | (Ce,La)(CO₃)F | USA, China, Kazakhstan |
Monazite | (Ce,La,Nd,Th)PO₄ | India (Kerala, Odisha), Brazil |
Xenotime | YPO₄ (contains heavy rare earths like Tb) | Malaysia, Australia, India |
Lateritic Ion-Exchange Clays | — | Southern China |
- Terbium is typically co-extracted along with other rare earths and separated by solvent extraction.
Other Major Rare Earth Elements
Element | Symbol | Major Ore | Application |
Neodymium | Nd | Monazite | Magnets, wind turbines, headphones |
Europium | Eu | Bastnasite | Red & blue phosphors in screens |
Dysprosium | Dy | Xenotime | Magnets, nuclear control rods |
Yttrium | Y | Xenotime | Superconductors, LEDs |
Cerium | Ce | Monazite | Catalytic converters, glass polishing |